Title: Palladium-Catalyzed Cross-Coupling Reaction of Arenediazonium Salts with Alkyl Chloroformates
Volume: 4
Issue: 8
Author(s): Rolando Perez, Daniela de Luna Martins, Lucia C.S. Aguiar, Heiddy M. Alvarez, L. Cardozo-Filho, Aline V. Coelho and O. A.C. Antunes
Affiliation:
Keywords:
Palladium, chloroformate, arenediazonium, cross-coupling
Abstract: The first palladium – catalyzed cross-coupling reaction between arenediazonium tetrafluoroborate salts and chloroformates to afford the corresponding substituted aryl carboxylic esters, in the presence of catalytic amounts of Pd(OAc)2 is described.