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Review Article

Dess-Martin Periodinane (DMP) in Organic Synthesis-A Septennial Update (2015-till Date)

Author(s): Ravi Varala*, Vittal Seema, Mohammed Mujahid Alam*, Mohammed Amanullah and Narsimhaswamy Dubasi

Volume 27, Issue 17, 2023

Published on: 25 October, 2023

Page: [1504 - 1530] Pages: 27

DOI: 10.2174/0113852728262311231012060626

Price: $65

Abstract

Dess-Martin periodinane (DMP) is one of the hypervalent iodines that is most frequently utilized as an oxidizing agent in organic chemistry. The authors of this septennial review have critically and methodically presented representative applications of DMP in organic synthesis from 2015 to the present, including oxidations, dehydrogenations, hetero and homo-dimerizations, aromatizations, thiocyanations, halogenations, dearylations, ring expansions, cyclizations, heterocyclic ring formation, and other miscellaneous reactions. This review discusses the range and constraints of these transformations.

Keywords: Dess-Martin Periodinane (DMP), oxidation, cyclization, dehydrogenation, dearylation, ring expansion.

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