Synthesis and Cation Binding Properties of p-Tert-butyl-calix[4]arene Bearing 8-Hydroxyquinoline Units

Title:Synthesis and Cation Binding Properties of p-Tert-butyl-calix[4]arene Bearing 8-Hydroxyquinoline Units

Volume: 15 Issue: 12

Author(s): Slim Mannai, Yang Kim, Abdullah Sulaiman Al-Ayed, Lassaad Baklouti*Abdelwaheb Hamdi

Affiliation:

• Department of Chemistry and Advanced Materials, Kosin University, 149-1, Dongsam-dong, Yeongdo-gu, Busan 606-701,South Korea

Keywords: Calixarene, hydroxyquinoline, complexation, stability constant, extraction, ligands.

Abstract: We report the synthesis and complexation properties of two new hydroxyquinolinecalixarene derivatives 1 and 2. The complexation studies of the synthesized ligands toward lanthanide cations have been monitored by UV absorption spectrophotometry and conductimetric in acetonitrile. The extraction properties into water to dichloromethane of 1 and 2 toward La(III), Gd(III) and Yb(III) have been also determined.

Cite this article as:

Mannai Slim , Kim Yang , Al-Ayed Sulaiman Abdullah , Baklouti Lassaad *, Hamdi Abdelwaheb , Synthesis and Cation Binding Properties of p-Tert-butyl-calix[4]arene Bearing 8-Hydroxyquinoline Units, Letters in Organic Chemistry 2018; 15 (12) . https://dx.doi.org/10.2174/1570178615666180430120945