Abstract
In this paper, a novel secondary dialkylammonium salt with three stations (G1) was synthesized in 5 steps. 1H NMR was used to study the threading of G1 through the cavity of dibenzo-24-crown-8 (DB24C8) and benzo-21-crown-7 (B21C7). The complexation of G1 and two crown ethers was proved to be slow-exchange systems. This result lays the foundation on the integrative self-sorting organization of G1, DB24C8 and B21C7.
Keywords: Secondary dialkylammonium salts with three stations, crown ether, 1H NMR, threading
Letters in Organic Chemistry
Title:Synthesis of a Novel Secondary Dialkylammonium Salt with Three Stations and its Threading Through the Cavity of Two Crown Ethers
Volume: 10 Issue: 2
Author(s): Jianfen Shen, Yan Luo, Rener Chen, Deman Han, Huajiang Jiang and Qizhong Zhou
Affiliation:
Keywords: Secondary dialkylammonium salts with three stations, crown ether, 1H NMR, threading
Abstract: In this paper, a novel secondary dialkylammonium salt with three stations (G1) was synthesized in 5 steps. 1H NMR was used to study the threading of G1 through the cavity of dibenzo-24-crown-8 (DB24C8) and benzo-21-crown-7 (B21C7). The complexation of G1 and two crown ethers was proved to be slow-exchange systems. This result lays the foundation on the integrative self-sorting organization of G1, DB24C8 and B21C7.
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Cite this article as:
Shen Jianfen, Luo Yan, Chen Rener, Han Deman, Jiang Huajiang and Zhou Qizhong, Synthesis of a Novel Secondary Dialkylammonium Salt with Three Stations and its Threading Through the Cavity of Two Crown Ethers, Letters in Organic Chemistry 2013; 10 (2) . https://dx.doi.org/10.2174/1570178611310020006
DOI https://dx.doi.org/10.2174/1570178611310020006 |
Print ISSN 1570-1786 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6255 |
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