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Current Organic Chemistry

Editor-in-Chief

ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

Review Article

Synthesis of Polynuclear Aromatic Hydrocarbons by Palladium-catalyzed C-H Bond Functionalization

Author(s): Mitali Dewan, Sachinath Bera, Shubhankar Samanta, Debasish Kundu* and Rathin Jana*

Volume 28, Issue 18, 2024

Published on: 21 June, 2024

Page: [1387 - 1403] Pages: 17

DOI: 10.2174/0113852728283702240605113835

Price: $65

Abstract

Nowadays palladium-catalyzed C–H bond activation is a useful approach for the synthetic transformation of organic compounds due to step economy, the use of non-prefunctionalized substrates and reduced chemical wastes. Among the various synthetic strategies, palladium catalyzed intra and inter-molecular C–H bond activation has recently drawn a lot of interest to synthesize the decorated π-conjugated polycyclic aromatic hydrocarbon. In this review, we have focused on recent progress along with previous strategies to synthesize various polynuclear aromatic hydrocarbons (PAHs) by the use of Pd-catalyzed C–H bond activation. We have also discussed the mechanistic details of the reaction intra and inter-molecular C–H bond activation.

Keywords: C-H activation, Pd-catalyzed, PAH, phenanthrene, heck reaction, aromatic hydrocarbons.

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