Title:Tailoring Ti3C2Tx MXene Flake Sizes for Modified Electrochemical
Performance: A Top-down Approach
Volume: 1
Author(s): Yuchao Fan, Xu Mei, Li Ye*, Qingyong Tian, Renqi Zhang, Yingjiu Zhang and Xinjian Li
Affiliation:
- School of Materials Science and Engineering, Zhengzhou University, Zhengzhou, 450001, China
Keywords:
Mxene, Ti3C2Tx, supercapacitors, size, large-scale, ball milling, gravimetric capacitance, hydrophilic surface.
Abstract:
Introduction: Two-dimensional (2D) materials, such as MXene (Ti3C2Tx), have
garnered extensive attention in recent years due to their exceptional performance across various
domains. The flake size of Ti3C2Tx notably influences its specific surface area, a pivotal factor
in interfacial interactions within electrochemistry.
Method: Presently, modifying the flake size of bulk Ti3C2Tx typically involves complex and
costly processes, like ultrasonic treatment and isolation. Leveraging the specific preparation
principle of MXenes, which involves etching the A layers in precursor MAX phases, a topdown
strategy for producing Ti3C2Tx flakes of desired sizes, has been proposed in this work. In
this approach, precursor Ti3AlC2 particles undergo ball-milling to adjust their size.
Result: Through this innovative strategy, dispersions of Ti3C2Tx flakes with varying average
lateral sizes are generated, enabling an investigation into the impact of lateral size on the electrochemical
properties of Ti3C2Tx flakes. By controlling the ball milling time for Ti3AlC2 powders,
the resulting average sizes of Ti3C2Tx (0, 2, 4) are 6.34 μm, 2.16 μm, and 0.96 μm, respectively.
Particularly, the Ti3C2Tx (2) electrode, composed of 2.16 μm sheets, demonstrates remarkable
performance metrics. It exhibits a high areal capacitance of 845.0 mF/cm2 at a scan
rate of 5 mV/s, along with a gravimetric capacitance of 244.0 F/g at a current density of 1 A/g.
Conclusion: This study presents a facile method to enable mass production of Ti3C2Tx with
sheets of varying sizes, addressing both small and large dimensions.
