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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Mini-Review Article

Synthesis of Carboxylic Acid by Electrochemical Fixation of Carbon Dioxide: A Review of Electrochemical Carboxylation from Past to Latest

Author(s): Hisanori Senboku*

Volume 28, Issue 2, 2024

Published on: 04 October, 2023

Page: [76 - 88] Pages: 13

DOI: 10.2174/1385272827666230915162055

Price: $65

Abstract

Electrochemical reduction of organic compounds in the presence of carbon dioxide results in the fixation of carbon dioxide into the substrates with carbon-carbon bond forming reaction to yield the corresponding carboxylic acids. The reaction is called “electrochemical carboxylation” or “electrocarboxylation”. Various kinds of carboxylic acids have been synthesized using carbon dioxide as a carboxyl group source by electrochemical carboxylation. In this mini-review, several representative kinds of carboxylic acids synthesized from carbon dioxide by electrochemical carboxylation are briefly summarized/introduced, comparing past and latest.

Keywords: Electrochemical carboxylation, fixation of carbon dioxide, carboxylic acids, sacrificial anode, electroorganic synthesis, amino acids, undivided cell, carbon-carbon bond forming reaction.

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