Title:Electronic and Magnetic Properties of Eutectoid Growth Mn-rich
Ge1-xMnx Dilute Magnetic Semiconductors
Volume: 2
Issue: 2
Author(s): Xiuxiu Zhang, Hui Su and Qinghua Liu*
Affiliation:
- National Synchrotron Radiation Laboratory, University of Science and Technology of China, Hefei 230029, Anhui, P.R.
China
Keywords:
Dilute magnetic semiconductors, electronic structure, band structure, doping, ferromagnetism, Mn dopant, Mn-rich.
Abstract: Background: Dilute magnetic semiconductors (DMSs) have attracted great attention in
recent years due to their potential applications in spintronic devices.
Objective: This study aimed to investigate the magnetic and electronic properties of Mn-rich Ge
semiconductors.
Methods: The magnetic and electronic properties of eutectoid growth Mn-rich Ge1-xMnx dilute magnetic
semiconductors (DMSs) with a high Mn dopant close to the composition of Ge2Mn are investigated
by the first-principles calculations.
Results: Using the diamond structure models of Ge24Mn8, Ge22Mn10, and Ge20Mn12, we show that
the magnetic interactions of Mn atoms are dominated by ferrimagnetic coupling and that the Mn 3d
states are substantially hybridized with the valence bands of the Ge matrix.
Conclusion: This indicates that Mn-rich Ge1-xMnx DMSs demonstrate a ferromagnetic and metallic
character, and their carriers can mobilize in the lattice more freely. The present investigation could
provide insights into understanding the nature of transition-metal-rich dilute magnetic semiconductors.