Title:Carboxylate-Functionalized P, N-Ligated Cobalt Catalysts for Alkene Hydrosilylation
Volume: 18
Issue: 5
Author(s): Yangyang Ma, Jiayun Li*, Ying Bai and Jiajian Peng*
Affiliation:
- Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121,China
- Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, Hangzhou Normal University, Hangzhou 311121,China
Keywords:
Cobalt complex, N, P-Ligands, hydrosilylation, alkene, KOtBu, facile.
Abstract: A series of N, P-ligands bearing carboxyl groups have been synthesized. These have been applied in
conjunction with cobalt naphthenate in a facile, economic, and efficient method for the catalytic hydrosilylation
of alkenes. In the presence of KOtBu as an additive, the reaction time and activation energy are greatly reduced.