Some physico-chemical properties of hyperbranched poly([1,2,3]-triazol-[1,3,5]-triazine)s synthesized by thermal azide-alkyne cycloaddition of AB2 and A2B monomers were studied by DSC, TGA, SEC and other methods. Density, thermal stability, shock and friction sensitivity were determined. The combustion heat of monomers and polymers, which was also defined, was used to compute their heat. The thermodynamical compatibility of polymers with various plasticizers was investigated by the micro-interference method in the temperature range from 20°C to 100° C. The phase state diagrams were plotted based on the mutual solubility of polymers with plasticizer’s data. The interdiffusion coefficients were found in a wide range of temperatures and solution compositions of investigated systems. Hyperbranched poly([1,2,3]-triazole-[1,3,5]-triazine)s are the perfect building blocks for the creation of innovative energy materials because of their unique features.
Keywords: Density, Heat of formation, Hyperbranched poly([1, 2, 3]-triazol- -[1, 3, 5]-triazine)s, Plasticizer, Sensitivity, Stability, Thermodynamic compatibility.
