Abstract
MCM-41-SO3H as an ordered mesoporous silica material in which MCM-41 with covalently anchored sulfonic acid groups located inside the meso channels, was used as an acidic catalyst for the rapid and ‘green’ synthesis of N-aryl-2-amino-1,6-naphthyridine derivatives under solvent-free conditions. This nanocatalyst was characterized by X-ray powder diffraction, Fourier-transfer infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), Nitrogen adsorption-desorption analysis and acid-base titration. This novel synthetic method is especially favoured because it provides a synergy of the nanosized MCM-41-SO3H and solvent-free conditions which offers the advantages of high yields, simplicity and easy workup compared to the conventional method reported in the literature. Most significantly, this solid acidic catalyst is found to be very efficient and reusabile for a number of times and showed consistent activity.
Keywords: Nanocatalyst, MCM-41-SO3H, N-aryl-2-amino-1, 6-naphthyridine, Solvent free conditions.
Current Nanoscience
Title:MCM-41-SO3H as an Advanced Nanocatalyst for the Solvent-Free Synthesis of N-aryl-2-amino-1,6-naphthyridine Derivatives
Volume: 8 Issue: 5
Author(s): Shahnaz Rostamizadeh, Nasrin Shadjou and Atena Fazelzadeh
Affiliation:
Keywords: Nanocatalyst, MCM-41-SO3H, N-aryl-2-amino-1, 6-naphthyridine, Solvent free conditions.
Abstract: MCM-41-SO3H as an ordered mesoporous silica material in which MCM-41 with covalently anchored sulfonic acid groups located inside the meso channels, was used as an acidic catalyst for the rapid and ‘green’ synthesis of N-aryl-2-amino-1,6-naphthyridine derivatives under solvent-free conditions. This nanocatalyst was characterized by X-ray powder diffraction, Fourier-transfer infrared spectroscopy (FT-IR), Scanning electron microscopy (SEM), Nitrogen adsorption-desorption analysis and acid-base titration. This novel synthetic method is especially favoured because it provides a synergy of the nanosized MCM-41-SO3H and solvent-free conditions which offers the advantages of high yields, simplicity and easy workup compared to the conventional method reported in the literature. Most significantly, this solid acidic catalyst is found to be very efficient and reusabile for a number of times and showed consistent activity.
Export Options
About this article
Cite this article as:
Rostamizadeh Shahnaz, Shadjou Nasrin and Fazelzadeh Atena, MCM-41-SO3H as an Advanced Nanocatalyst for the Solvent-Free Synthesis of N-aryl-2-amino-1,6-naphthyridine Derivatives, Current Nanoscience 2012; 8 (5) . https://dx.doi.org/10.2174/157341312802884571
DOI https://dx.doi.org/10.2174/157341312802884571 |
Print ISSN 1573-4137 |
Publisher Name Bentham Science Publisher |
Online ISSN 1875-6786 |
Call for Papers in Thematic Issues
Advanced Inorganic Nanocomposites and Their Emerging Applications
This special issue collection will highlight developments on the recent trends about the synthesis of metal oxides, nanoclusters, biomaterials, 2D nanomaterials, nanocrystals, nanocomposites, etc. and their applications in electrochemical systems, tissue regeneration, energy storage and harvesting, sensors, etc. The novelty of the methods in the chemical synthesis and their characterizations, ...read more
Advanced Nanotechnology in Forensic Science: Revolutionizing Fingerprint Identification and Crime Scene Analysis
This special issue aims to provide a comprehensive exploration of the innovative fusion between nanotechnology and forensic science. It aspires to bridge the gap between traditional investigative techniques and cutting-edge nanoscale applications, envisioning a paradigm shift in forensic analysis. By compiling the expertise of multidisciplinary experts, the book's objectives include ...read more
Graphene and 2D Materials for Energy Storage and Conversion
This thematic issue will discuss the recent advances in graphene-based nanomaterials for different energy technologies. Graphene possesses a high surface area, and stable structure and exhibits many interesting electronic, optical, and mechanical properties due to its 2D crystal structure. Graphene is of both fundamental interest and suitable for a wide ...read more
Nanotechnology: Enhancing Efficiency and Safety in Environmental Pollution Remediation
This special issue delves into the transformative role of nanotechnology in addressing pressing environmental challenges. Nanomaterials, armed with their unique properties, are at the forefront of combating water contamination by removing heavy metals, pesticides, and even nanoplastics from aquatic ecosystems. In the realm of soil remediation, nanotechnology is revitalizing contaminated ...read more
Related Journals
![](/images/wayfinder.jpg)
- Author Guidelines
- Graphical Abstracts
- Fabricating and Stating False Information
- Research Misconduct
- Post Publication Discussions and Corrections
- Publishing Ethics and Rectitude
- Increase Visibility of Your Article
- Archiving Policies
- Peer Review Workflow
- Order Your Article Before Print
- Promote Your Article
- Manuscript Transfer Facility
- Editorial Policies
- Allegations from Whistleblowers
Related Articles
-
Artificial O2 Carriers: Status in 2005
Current Pharmaceutical Design How to Identify Subjects with Poly-Vascular Disease?
Current Vascular Pharmacology A Review of the Treatment of Psoriasis with Infliximab
Reviews on Recent Clinical Trials Effectiveness and Safety of Digoxin on Chronic Heart Failure
Current Pharmaceutical Analysis Antioxidant Therapy for Prevention of Inflammation, Ischemic Reperfusion Injuries and Allograft Rejection
Cardiovascular & Hematological Agents in Medicinal Chemistry Marinobufagenin in Urine: A Potential Marker of Predisposition to Ethanol and a Target for Spironolactone
Current Hypertension Reviews N-acetyl-seryl-aspartyl-lysyl-proline (Ac-SDKP): Potential target molecule in research of heart, kidney and brain
Current Pharmaceutical Design MiR-106a Associated with Diabetic Peripheral Neuropathy Through the Regulation of 12/15-LOX-meidiated Oxidative/Nitrative Stress
Current Neurovascular Research Dietary Fatty Acids in Metabolic Syndrome, Diabetes and Cardiovascular Diseases
Current Diabetes Reviews The Interplay Between Asthma and Other Diseases: Role of Ca2+/cAMP Signalling
Endocrine, Metabolic & Immune Disorders - Drug Targets Nonfasting Hyperlipidemia and Cardiovascular Disease
Current Drug Targets PUFA for Prevention and Treatment of Dementia?
Current Pharmaceutical Design Cyclooxygenase Inhibitors: Instrumental Drugs to Understand Cardiovascular Homeostasis and Arterial Thrombosis
Cardiovascular & Hematological Disorders-Drug Targets Ethosomes as Novel Vesicular Carrier: An Overview of the Principle, Preparation and its Applications
Current Drug Delivery Comparison of Different Treatment Regimens for Long-term Improvement of Renal Function in Patients with Henoch-Schönlein Purpura: A Systematic Review
Current Rheumatology Reviews Cell-Selective Mitochondrial Targeting: Progress in Mitochondrial Medicine
Current Drug Delivery Association of Low BMI with Aortic Stiffness in Young Healthy Individuals
Current Hypertension Reviews Higher Waist Circumference, Fasting Hyperinsulinemia And Insulin Resistance Characterize Hypertensive Patients With Impaired Glucose Metabolism
Endocrine, Metabolic & Immune Disorders - Drug Targets Anaphylaxis in Risky Populations
Current Pharmaceutical Design Novel Inflammatory Biomarkers in Cardiovascular Therapeutics
Current Medicinal Chemistry