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Current Organic Chemistry

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ISSN (Print): 1385-2728
ISSN (Online): 1875-5348

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Letter Article

A Banana-like Ni-MgO Solid Solution Catalyst Derived from Bimetallic Ni-Mg@MOFs for Hydrogenation of Nitroarenes

Author(s): Weizuo Li, Rui Fu, Xue Luo* and Xin Wang*

Volume 27, Issue 6, 2023

Published on: 13 July, 2023

Page: [465 - 470] Pages: 6

DOI: 10.2174/1385272827666230608154543

Price: $65

Abstract

The design and synthesis of an efficient Ni-MgO solid solution catalyst with specific morphology for the hydrogenation of nitroarenes is highly required. In this work, a banana- like Ni-MgO solid solution incorporation of carbon catalyst (termed as Ni/MgO-C) has been synthesized via a MOFs-templating strategy for one-step pyrolysis of bimetallic Ni- Mg@MOFs.

The developed Ni/MgO-C catalyst was applied to the hydrogenation of nitroarenes reaction, which exhibited good performance for the hydrogenation of nitroarenes to the corresponding arylamines.

The Ni-Mg@MOFs served as a precursor for the preparation of a solid solution catalysts that could improve the dispersion of Ni species, reduce the size of metallic Ni, and strengthen the Ni-MgO interaction, enhance the transfer of electron density. All of these are beneficial for improving the performance of the hydrogenation process.

This MOFs-templating strategy may provide a facile method for the synthesis of Ni-MgO solid solution catalyst for other hydrogenation reactions.

Keywords: Metal-organic frameworks, templated strategy, hydrogenation, nitroarenes, Ni-MgO, solid solution.

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