Synthesis of 4-oxo-2,5-cyclopentadiene Using Multi-component Reactions of Primary Amines and Electron Deficient Acetylenic Compounds with Triphenylphosphine in Water

ISSN: 1875-6255 (Online)
ISSN: 1570-1786 (Print)


Volume 11, 10 Issues, 2014


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Letters in Organic Chemistry

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Editor-in-Chief:
Miguel Yus
Universidad de Alicante Apdo
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Synthesis of 4-oxo-2,5-cyclopentadiene Using Multi-component Reactions of Primary Amines and Electron Deficient Acetylenic Compounds with Triphenylphosphine in Water

Author(s): Samereh Seyfi, Faramarz Rostami-Charati, Zinatossadat Hossaini and Mohammad R. Zardoost

Affiliation: Department of Chemistry, Faculty of Science, Gonbad Kavous University, P.O. Box 163, Gonbad, Iran.

Abstract

A water-accelerated multicomponent synthesis of organic target molecules has been used as a key method for the preparation of cyclopentadiene derivatives. The three-component condensation reactions of primary amines with alkyl propiolates in the presence of triphenylphosphine in water at 80 °C are developed as efficient and clean green synthetic procedures for the high-yielding preparation of 4-oxo-2,5-cyclopentadiene-1,2-dicarboxylate derivatives.




Keywords: Cyclopentadiene, primary amines, triphenylphosphine, alkyl propiolates, multi-component reaction.

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Article Details

Volume: 11
Issue Number: 6
First Page: 409
Last Page: 412
Page Count: 4
DOI: 10.2174/157017861106140413171933
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