Controlling Photoinduced Electron Transfer Via Defects Self-Organization for Novel Functional Macromolecular Systems

ISSN: 1875-5550 (Online)
ISSN: 1389-2037 (Print)

Volume 18, 12 Issues, 2017

Download PDF Flyer

Current Protein & Peptide Science

This journal supports open access

Aims & ScopeAbstracted/Indexed in

Submit Abstracts Online Submit Manuscripts Online

Ben M. Dunn
Department of Biochemistry and Molecular Biology University of Florida
College of Medicine, P.O. Box 100245, Gainesville
Florida, FL 32610-0245

View Full Editorial Board

Subscribe Purchase Articles Order Reprints

Current: 2.441
5 - Year: 2.705

Controlling Photoinduced Electron Transfer Via Defects Self-Organization for Novel Functional Macromolecular Systems

Current Protein & Peptide Science, 15(4): 394-399.

Author(s): Gaetano Campi, Gabriele Ciasca, Nicola Poccia, Alessandro Ricci, Michela Fratini and Antonio Bianconi.

Affiliation: Institute of Crystallography, Via Salaria Km 29.300, 00015, Monterotondo Roma, Italy.


The electrons transfer (ET) from an atom or a molecule, donor (D), to another, acceptor (A) is the basis of many fundamental chemical and physical processes. The ET mechanism is controlled by spatial arrangements of donor and acceptors: it’s the particular spatial arrangement and thus the particular distance and the orientation between the electron donors and acceptors that controls the efficiency in charge separation processes in nature. Here, we stress the importance of this concept reviewing how spatial distribution of atomic and molecular self-assembly can determine the quality and physical features of ET process from biology to material science. In this context, we propose novel lab-on-chip techniques to be used to control spatial distribution of molecules at nanoscale. Synchrotron source brightness jointly to focusing optics fabrication allows one nowadays to monitor and visualize structures with sub-micrometric spatial resolution. This can give us a new powerful tool to set up sophisticated X-ray imaging techniques as well as spectroscopic elemental and chemical mapping to investigate the structure-function relationship controlling the spatial arrangement of the molecules at nanoscale. Finally, we report intriguing recent case studies on the possibility to manipulate and control this spatial distribution and material functionality at nanoscale by using X ray illumination.


Charge separation, electron transfer, lab on chip, photo-induced phase transition, synchrotron radiation, X-ray micro- diffraction.

Download Free Order Reprints Order Eprints Rights and Permissions

Article Details

Volume: 15
Issue Number: 4
First Page: 394
Last Page: 399
Page Count: 6
DOI: 10.2174/1389203715666140327104023

Related Journals

Webmaster Contact: Copyright © 2016 Bentham Science