Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

ISSN: 1877-9476 (Online)
ISSN: 1877-9468 (Print)


Volume 5, 4 Issues, 2015


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Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium


Current Physical Chemistry, 4(3): 302-309.

Author(s): Deepmala Pareek, Riya Sailani, Vinita K. Gupta, Chandra L. Khandelwal and Prem D. Sharma

Affiliation: Department of Chemistry, University of Rajasthan, Jaipur 302055, India.

Abstract

The kinetics and mechanism of oxidation of paracetamol (PCM) by thallium (III) in acid perchlorate medium has been studied.

The reaction exhibits first order kinetics with respect to the oxidant but a complex dependence of the substrate. The rate is reduced by an increase in the hydrogen ion concentration in a complex manner. A plausible reaction mechanism has been suggested to account for experimental observations.


Keywords:

Kinetics, mechanism, oxidation, paracetamol, thallic perchlorate.



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Article Details

Volume: 4
Issue Number: 3
First Page: 302
Last Page: 309
Page Count: 8
DOI: 10.2174/1877946804666140429004357
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