Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

ISSN: 1877-9476 (Online)
ISSN: 1877-9468 (Print)


Volume 4, 4 Issues, 2014


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Current Physical Chemistry

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Editor-in-Chief:
Ruhong Zhou
IBM Thomas J. Watson Research Center and Columbia University
Yorktown Heights
NY 10598
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Kinetics and Mechanism of Oxidation of Paracetamol by Thallic Perchlorate in Acid Medium

Author(s): Deepmala Pareek, Riya Sailani, Vinita Kumari Gupta, C. L. Khandelwal and P. D. Sharma

Affiliation: Department of Chemistry, University of Rajasthan, Jaipur (India) 302055.

Abstract

The kinetics and mechanism of oxidation of paracetamol(PCM) by thallium (III) in acid perchlorate medium has been studied.

The reaction exhibits first order with respect to the oxidant but complex dependence of the substrate.Rate is retarded by hydrogen ion concentration in a complex manner. A plausible reaction mechanism has been suggested to account for experimental observations.



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Article Details

Volume: 4
First Page: 1
Page Count: 1
DOI: 10.2174/1877946804666140429004357
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